- journal_title：American Mineralogist
- Contributor：Orazio Ferro ; Simona Quartieri ; Giovanna Vezzalini ; Chiara Ceriani ; Ettore Fois ; Aldo Gamba ; Giuseppe Cruciani
- Publisher：Mineralogical Society of America
- Date：2004-
- Format：text/html
- Language：en
- journal_abbrev：American Mineralogist
- issn：0003-004X
- volume：89
- issue：1
- firstpage：94
- section：Articles
The thermal dehydration process of the natural Li zeolite bikitaite has been studied in situ by synchrotron radiation powder diffraction. The temperature-resolved experiments were performed using a translating imaging plate system. Rietveld refinements were carried out on 42 powder patterns in the temperature range from room temperature to 800 °C. Bikitaite is stable at least up to 800 °C, the temperature at which the phase transition to γ-spodumene begins. The dehydration process begins at about 200 °C, affecting the two water sites in a similar way, and is complete at 468 °C. Such a process induces only very minor structural distortions in the framework, due to the anti-rotation of the internal T-O-T hinges. In this sense, bikitaite can be defined as a flexible but non-collapsible framework, and it is the zeolite that undergoes the lowest heating-induced distortion among those studied up to now. The high thermal and structural stability suggest that anhydrous bikitaite could be used as a solid porous matrix for embedding nanosized materials in its one-dimensional channels.