• journal_title：Mineralogical Magazine
• Contributor：Lidong Dai ; Heping Li ; Chunhai Li ; Haiying Hu ; Shuangming Shan
• Publisher：Mineralogical Society of Great Britain and Ireland
• Date：2010-
• Format：text/html
• Language：en
• Identifier：10.1180/minmag.2010.074.5.849
• journal_abbrev：Mineralogical Magazine
• issn：0026-461X
• volume：74
• issue：5
• firstpage：849
• section：Articles

The electrical conductivity of dry polycrystalline olivine compacts (hot-pressed and sintered pellets) was measured at pressures of 1.0–4.0 GPa, at temperatures of 1073–1423 K, and at different oxygen fugacities via the use of a YJ-3000t multi-anvil press. Oxygen fugacity was controlled successfully by means of five solid buffers: Fe₃O₄-Fe₂O₃, Ni-NiO, Fe-Fe₃O₄, Fe-FeO and Mo-MoO₂. Within the selected frequency range of 10²–10⁶ Hz, the experimental results indicate that the grain interior conduction mechanism is characterized by a semi-circular curve on an impedance diagram. As a function of increasing pressure, the electrical conductivity of polycrystalline olivine compacts decreases, whereas the activation enthalpy and the temperature-independent pre-exponential factors increase slightly. The activation energy and activation volume of polycrystalline olivine compacts were determined to be 141.02±2.53 kJ/mol and 0.25±0.05 cm³/mol, respectively. At a pressure of 4.0 GPa, electrical conductivity was observed to increase as a function of increasing oxygen fugacity, and the relationship between electrical conductivity and oxygen fugacity can be described as log₁₀ (σ) = (2.47±0.085) + (0.096±0.023)×log₁₀ f_O2 +(−0.55±0.011)/T, which presents the exponential factor q (∼0.096). Our observations demonstrate that the primary conduction mechanism for polycrystalline olivine compacts is a small polaron.