• journal_title：American Mineralogist
• Contributor：Daniel R. Neuville ; Laurent Cormier ; Valérie Montouillout ; Pierre Florian ; Francis Millot ; Jean-Claude Rifflet ; Dominique Massiot
• Publisher：Mineralogical Society of America
• Date：2008-
• Format：text/html
• Language：en
• Identifier：10.2138/am.2008.2867
• journal_abbrev：American Mineralogist
• issn：0003-004X
• volume：93
• issue：11-12
• firstpage：1721
• section：Amorphous Materials: Properties, Structure, and Durability

The structure and properties of glasses and melts in the MgO-Al₂O₃-SiO₂ (MAS) and CaO-MgO-Al₂O₃-SiO₂ (CMAS) systems play an important role in Earth and material sciences. Aluminum has a crucial influence in these systems, and its environment is still questioned. In this paper, we present new results using Raman spectroscopy and ²⁷Al nuclear magnetic resonance on MAS and CMAS glasses. We propose an Al/Si tetrahedral distribution in the glass network in different Qⁿ species for silicon and essentially in Q⁴ and ^VAl for aluminum. For the CMAS glasses, an increase of ^VAl and ^VIAl is clearly visible as a function of the increase of Mg/Ca ratio in the (Ca,Mg)₃Al₂Si₃O₁₂ (garnet) and (Ca,Mg)AlSi₂O₈ (anorthite) glass compositions. In the MAS system, the proportion of ^VAl and ^VIAl increases with decreasing SiO₂ and, similarly with calcium aluminosilicate glasses, the maximum of ^VAl is located in the center of the ternary system.