Characterizing the physical properties and identifying boundaries within active accretionary prisms is necessary in understanding their behaviour and recent movement. In such unstable conditions core recovery is not always reliable, especially around fault zones. Integrated Ocean Drilling Program (IODP) Expedition 314 was the first stage of the Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE), and used logging-while-drilling (LWD) technology to record continuous physical property data. We use iterative non-hierarchical cluster analysis (INCA) to quantitatively define the characteristics of the slope sediments and sediments within the accretionary prism at Sites C0001 and C0004. A new and detailed log-based lithostratigraphy is developed, and positions of major boundaries, defined by 3D seismic profiles and initial interpretation of log responses, are refined. The results produce clusters that clearly distinguish the slope sediments and characterize formations within the accretionary prism. Boundaries that correlate to the seismic-defined unconformity between the slope sediments and the accretionary prism, and a boundary within the accretionary prism that corresponds to a megasplay fault previously unresolved by log analysis and borehole images, are identified. Our study demonstrates that INCA analysis of LWD data can accurately define boundaries and characterize sediments in environments where core recovery may be incomplete.