High P-T phase relation of magnesian (Mg0.7Fe0.3) staurolite compositon in the system FeO-MgO-Al2O3-
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  • journal_title:American Mineralogist
  • Contributor:Kei Sato ; M. Santosh ; Toshiaki Tsunogae
  • Publisher:Mineralogical Society of America
  • Date:2010-
  • Format:text/html
  • Language:en
  • Identifier:10.2138/am.2010.3170
  • journal_abbrev:American Mineralogist
  • issn:0003-004X
  • volume:95
  • issue:1
  • firstpage:177
  • section:Articles
摘要

High-pressure and high-temperature phase relation on Mg0.74Fe0.26-staurolite composition with excess water in the system FeO-MgO-Al2O3-SiO2-H2O was experimentally determined at 12–19 kbar and 850–1050 °C, with a focus on the lower-pressure stability limit of magnesian staurolite. The experimental results show that the stability field of staurolite in the system shifts to higher temperatures as compared to that of pure-Mg staurolite. At 950 °C, the lower-pressure stability limit is located between 15 and 14 kbar. This study demonstrates that staurolite breaks down with isothermal decompression by a series of reactions at 950 °C: St → Opx + Crn + Melt and St + Opx → Spr + Melt. The Mg′ [=Mg/(Fe+Mg)] of staurolite in the former reaction is 0.7. When staurolite coexists with orthopyroxene in run products, the staurolite Mg′ is decreased to 0.6–0.5. Moderate-Mg staurolite (Mg′ = ~0.5) in natural occurrences has been reported as inclusion minerals in poikiloblastic garnets within ultrahigh-temperature (UHT) metamorphic rocks from major collisional orogenic belts in southern India and southern Africa. The experimental data presented in our study suggest the possibility that the staurolite-bearing UHT metamorphic rocks had experienced high-pressure metamorphism and/or UHT extreme metamorphism during the prograde metamorphic stage.

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