• journal_title：European Journal of Mineralogy
• Contributor：Alf Olav LARSEN ; Fred Steinar NORDRUM ; Nicola DÖBELIN ; Thomas ARMBRUSTER ; Ole V. PETERSEN ; Muriel ERAMBERT
• Publisher：E. Schweizerbart'sche Verlagsbuchhandlung Science Publishers
• Date：2005-
• Format：text/html
• Language：en
• Identifier：10.1127/0935-1221/2005/0017-0143
• journal_abbrev：Eur J Mineral
• issn：0935-1221
• volume：17
• issue：1
• firstpage：143
• section：Articles

Heulandite-Ba, ideally (Ba,Ca,Sr,K,Na)₅Al₉Si₂₇O₇₂·22H₂O, is a new zeolite species in the heulandite series, occurring as an accessory mineral in hydrothermal veins of the Kongsberg silver deposit type at the Northern RavnÅs prospect, southern Vinoren, 14 km NNW of Kongsberg town, Kongsberg ore district, Flesberg community, Buskerud county, Norway. The mineral has also been found at the Bratteskjerpet mine, Saggrenda near Kongsberg, and in hydrothermal veins in quartzite at Sjoa in Sel community, Oppland county. Heulandite-Ba occurs as well developed, thick tabular, trapezoidal crystals up to 4 mm across, showing the forms {100}, {010}, {001}, 1̄11} and {201̄}. The mineral is colourless to white, rarely very pale yellowish white or pale beige, with a white streak; transparent to translucent, with a vitreous lustre, pearly on {010}. The mineral has a perfect {010} cleavage; subconchoidal to uneven fracture. It is non-fluorescent in long- or short-wave ultraviolet light. The Mohs' hardness is 3½; D_meas = 2.35(1) and D_calc = 2.350 g/cm³. Heulandite-Ba is biaxial positive with n_α = 1.5056(5), n_β = 1.5064(5) and n_γ = 1.5150(5); Δ = 0.0094, n_(mean) = 1.5090. 2V_γ (calc) = 34.1°, 2V_γ(meas) = 38(1)°; distinct dispersion, r > v; α Λ c varying from ≅ 39° to ≅ 51° in obtuse angle β, γ = b. An average of 14 electron microprobe analyses on heulandite-Ba from the Northern RavnÅs prospect, Kongsberg, gave SiO₂ 54.26, Al₂O₃ 15.27, MgO < 0.1, CaO 2.65, SrO 1.03, BaO 12.76, Na₂O 0.34, K₂O 0.58, H₂O 13.1 (from TGA), total 99.99, corresponding to (Ba_2.49Ca_1.41Sr_0.30K_0.37Na_0.33)_Σ4.90Al_8.96Si_27.00O_72.00·21.75H₂Oon the basis of 72 framework oxygen atoms. Chemical zoning is frequent, with transitions to heulandite-Ca and heulandite-Sr.

Heulandite-Ba is monoclinic, C2/m, with a = 17.738(3), b = 17.856(2), c = 7.419(1) Å, β = 116.55(2)°, V = 2102.0(7) ų, Z = 1. The strongest five X-ray diffraction lines of the powder pattern [d in Å(I)(hkl)] are: 2.973(100)(151), 3.978(97)(131), 7.941(66)(200), 4.650(66)(-131), 2.807(65)(-621). The crystal structure refinements (R = 3.5%) of heulandite-Ba were done in space groups C2/m, Cm, C2, and C1̄, but refinements in space groups with lower symmetry than C2/m did not improve the structural model.