Bis(4′-phenyl-2,2′:6′,2″-terpyridine)ruthenium(II): Holding the {Ru(tpy)2}2+ embraces at bay
- 作者：Edwin C. Constable ; Catherine E. Housecroft ; Elaine A. Medlycott ; Markus Neuburger ; Federica Reinders ; Sé ; bastien Reymann ; Silvia Schaffner
- 关键词：2 ; 2′ ; 6′ ; 2′ ; ′ ; -Terpyridine ; Ruthenium ; Coordination ; Crystal structure ; Supramolecular
- 刊名：Inorganic Chemistry Communications
- 出版年：2008
- 期刊代码：39_13877003
- 类别：ch
- 出版时间：July 2008
- 卷：11
- 期：7
- 页码：805-808
- 文件大小：504 K
摘要
The solid state structure of [Ru(Phtpy)2][PF6]2 · 4MeCN has been determined (Phtpy = 4′-phenyl-2,2′:6′,2″-terpyridine); [Ru(Phtpy)2]2+ cations pack into sheets by virtue of {M(tpy)2}2 embraces, and the MeCN solvent molecules are involved in N
H–C interactions which prevent the efficient packing of adjacent sheets. Comparisons with related structures lead to some generalizations about packing motifs in salts containing [M(Phtpy)2]2+ or [M(pytpy)2]2+ cations (pytpy = 4′-pyridyl-2,2′:6′,2″-terpyridine).
H–C interactions which prevent the efficient packing of adjacent sheets. Comparisons with related structures lead to some generalizations about packing motifs in salts containing [M(Phtpy)2]2+ or [M(pytpy)2]2+ cations (pytpy = 4′-pyridyl-2,2′:6′,2″-terpyridine).