Geochemical evolution of groundwater in an alluvial aquifer: Case of El Eulma aquifer, East Algeria
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摘要
Hydrochemical, multivariate statistical and inverse hydrogeochemical modeling techniques were used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the El Eulma Mio-Plio-Quaternary aquifer, East Algeria. Cluster analysis based on major ion contents defined three main chemical water types, reflecting different hydrochemical processes. The first, group 1, has low salinity (mean EC = 937 渭S/cm) and abundance orders Ca2+ > Na+ 鈮?#xA0;Mg2+ > K+ and . With increased water-rock interaction, waters in groups 2 and 3 become more saline, changing composition towards Cl-HCO3-Ca and Cl-Ca-Na types. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area fall into three categories: (1) dissolution of evaporite minerals; (2) precipitation of carbonate minerals, quartz, kaolinite and Ca-smectite; (3) ion exchange.

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