A host-guest hybrid framework with Anderson anions as template: synthesis, crystal structure and photocatalytic properties

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• 作者：Hao Chen ; Haiyan An ; ^{anhy@dlut.edu.cn} ; Xuan Liu ; Huilong Wang ; Zhaofei Chen ; Hua Zhang ; Ying Hu
• 关键词：Host&ndash ; guest compound ; Anderson-anion template ; Photocatalytic properties
• 刊名：Inorganic Chemistry Communications
• 出版年：2012
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：July, 2012
• 卷：21
• 期：Complete
• 页码：65-68
• 文件大小：540 K

摘要

A new Anderson-anion-templated inorganic-organic hybrid compound, H[(bitdc)Ni(H₂O)₃]₂[IMo₆O₂₄]路6H₂O (1) (bitdc = N,N鈥?bis(isonicotinoyl)-trans-1,2-diaminocyclohexane), has been synthesized and characterized by elemental analysis, IR spectroscopy, TG analysis, Powder XRD and single鈥恈rystal X-ray diffraction. Compound 1 is made up of Anderson-type polyoxoanions [IMo₆O₂₄]^{5鈭?/sup> and dinuclear [(bitdc)₂Ni₂(H₂O)₆]4+ coordination complexes to yield an intriguing 3D supramolecular host-guest structure. To our best knowledge, compound 1 represents the first example of host-guest compounds with Anderson anions as template. The photocatalytic properties and magnetic properties of 1 have been investigated.}