Highly enantioselective aza-Morita–Baylis–Hillman reaction with a bisphenol-based bifunctional organocatalyst

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• 作者：Katsuji Ito ; Kanako Nishida ; Takashi Got ; a
• 关键词：Organocatalyst ; Allyl amine ; Aza-Morita&#x2013 ; Baylis&#x2013 ; Hillman reaction ; Hydrogen bonding
• 刊名：Tetrahedron Letters
• 出版年：2007
• 期刊代码：109_00404039
• 类别：ch
• 出版时间：27 August 2007
• 卷：48
• 期：35
• 页码：6147-6149
• 文件大小：122 K

摘要

Newly developed phosphino-bisphenol 1c was found to be an efficient organocatalyst for the aza-Morita–Baylis–Hillman reaction. High enantioselectivity up to 96%ee was obtained with catalyst loading of 1 mol%.