A chemoselective aerobic oxidation of benzylic azides catalyzed by molybdenum xanthate in an aqueous medium

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• 作者：Mahagundappa Maddani ; K ; ikere Ramaiah Prabhu
• 关键词：Benzyl azides ; Molybdenum ; Redox reactions ; Aerobic oxidations ; Chemoselectivity ; Green chemistry
• 刊名：Tetrahedron Letters
• 出版年：2008
• 期刊代码：109_00404039
• 类别：ch
• 出版时间：21 July 2008
• 卷：49
• 期：29-30
• 页码：4526-4530
• 文件大小：207 K

摘要

A mild molybdenum-catalyzed, aerobic, chemoselective oxidation of benzylic azides to the corresponding aldehydes in an aqueous medium that tolerates a variety of functional groups including alcohols, esters, ketones, halides and olefins is described.