New syntheses and solid state fluorescence of azomethine dyes derived from diaminomaleonitrile and 2,5-diamino-3,6-dicyanopyrazine
- 作者：Shirai ; Kazuko ; Matsuoka ; Masaru ; Fukunishi ; Koushi
- 关键词：2 ; 5-Diamino-3 ; 6-dicyanopyrazine ; Bisazomethine fluorescent dye ; New fluorescent chromophore ; Solid state fluorescence ; Fluorescence quenching ; EL emitter
- 刊名：Dyes and Pigments
- 出版年：2000
- 期刊代码：31_01437208
- 类别：ms
- 出版时间：October, 2000
- 卷：47
- 期：1-2
- 页码：107-115
- 文件大小：202 K
摘要
New fluorescent dyes of interest as red light emitters for electroluminescence devices were synthesized by the condensation of diaminomaleonitrile and 2,5-diamino-3,6-dicyanopyrazine with arylaldehydes. Substituent effects on their absorption and fluorescence spectra in the solution were determined by comparison with the parent chromophoric system. Their solid state absorption and fluorescence properties were evaluated with respect to their optimized molecular structures obtained by MOPAC methods.