High-pressure growth of Ca<sub>2鈭?/sub><sub>xsub>Na<sub>xsub>CuO<sub>2sub>Cl<sub>2sub> single crystals and pressure effect on superconductivity
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摘要
Single crystals of cuprate oxychloride superconductor Ca<sub>2鈭?/sub><sub>xsub>Na<sub>xsub>CuO<sub>2sub>Cl<sub>2sub> (Na-CCOC) with a systematic variant T<sub>csub> as a function of Na content are synthesized under high pressure and high temperature. The pressure effect on the superconducting transition temperature in Na-CCOC single crystal is investigated by electrical resistance measurements up to 6.5 GPa. It is found that the T<sub>csub> decreases almost linearly with increasing pressure, exhibiting a negative pressure shift, which is totally different pressure behavior from that of isostructural (La,Sr)2CuO<sub>4sub> and other cuprate superconductors.

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