A novel perchlorate-bridged tetranuclear zinc(II) structure with tris(2-aminoethyl)amine ligand

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• 作者：Fu ; Heng ; Liu ; Xue-Wen ; Zhou ; Zhong-Yuan ; Mao ; Zong-Wan ; Zheng ; Kang-Cheng ; Chen ; Xiao-Ming
• 关键词：Crystal structure ; Perchlorate-bridged ; Zinc tetramer ; MNDO calculation ; Tris(2-aminoethyl)amine
• 刊名：Inorganic Chemistry Communications
• 出版年：2004
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：July, 2004
• 卷：7
• 期：7
• 页码：906-908
• 文件大小：223 K

摘要

A highly symmetric zinc(II) complex with{[Zn(tren)]₄(μ₄-ClO₄)}⁷⁺ structure unit (tren=tris(2-aminoethyl)amine) was characterized by single-crystal X-ray diffraction and was understood by the calculation from the MNDO method.