Vapour pressure and excess Gibbs energy of binary 1,2-dichloroethane + cyclohexanone, chloroform + cyclopentanone and chloroform + cyclohexanone mixtures at temperatures

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• 作者：Dana Dragoescu ; Alex ; ru Barhala ; Mariana Teodorescu
• 关键词：Vapour– ; liquid equilibria ; Excess Gibbs energy ; Mixtures ; Cycloketones ; Chloroalkanes
• 刊名：Fluid Phase Equilibria
• 出版年：2008
• 期刊代码：32_03783812
• 类别：ce
• 出版时间：15 May 2008
• 卷：267
• 期：1
• 页码：70-78
• 文件大小：567 K

摘要

The vapour pressures of the binary systems 1,2-dichloroethane + cyclohexanone, chloroform + cyclopentanone and chloroform + cyclohexanone mixtures were measured at temperatures between 298.15 and 318.15 K. The vapour pressures vs. liquid phase composition data for three isotherms have been used to calculate the activity coefficients of the two components and the excess molar Gibbs energies, G^E, for these mixtures, using Barker's method. Redlich–Kister, Wilson, NRTL and UNIQUAC equations, taking into account the vapour phase imperfection in terms of the 2-nd virial coefficient, have represented the G^E values. No significant difference between G^E values obtained with these equations has been observed. Our data on vapour–liquid equilibria (VLE) and excess properties of the studied systems are examined in terms of the DISQUAC and modified UNIFAC (Dortmund) predictive group contributions models.