Production of hydrogen-rich fuels for pre-combustion carbon capture in power plants: A thermodynamic assessment

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• 作者：Fontina Petrakopoulou^a ; ^b ; ^{fontina.petrakopoulou@imdea.org} ; George Tsatsaronis^a
• 关键词：Hydrogen production ; Exergetic analysis ; Pre-combustion CO2 capture ; Combined-cycle power plant ; Methane steam reforming ; Autothermal reforming
• 刊名：International Journal of Hydrogen Energy
• 出版年：2012
• 期刊代码：42_03603199
• 类别：ch
• 出版时间：May, 2012
• 卷：37
• 期：9
• 页码：7554-7564
• 文件大小：1021 K

摘要

Hydrogen-fueled plants can play an important role in the field of carbon capture and storage, because they facilitate the mitigation of harmful emissions. In this paper, two combined-cycle power plants with pre-combustion CO₂ capture are examined, in which natural gas is converted into a hydrogen-rich fuel through reforming. The first plant considered operates with a hydrogen-separating membrane and the second with an autothermal reformer. The two plants are compared to a reference plant without CO₂ capture and briefly to alternative oxy-fuel and post-combustion capture technologies. It is found that both plants suffer high penalties caused by the high energy requirements of the reforming components and the CO₂ compression units. Additionally, both plants appear inferior to alternative capture technologies. When comparing the two reforming plants, the plant with the hydrogen-separating membrane operates somewhat more efficiently. However, in order to make these technologies more attractive, their thermodynamic efficiency must be enhanced. The potential for improving the efficiencies of these plants is revealed by an exergetic analysis.