Inorganic and organometallic hemicage podates and cage cryptates incorporating a benzene platform

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• 作者：Eli Zysman-Colman ; ^{Eli.Zysman-Colman@USherbrooke.ca} ; Cé ; line Denis
• 关键词：Hemicages ; Cages ; Capsules ; Metal complexes ; Host&ndash ; guest interactions ; Molecular recognition
• 刊名：Coordination Chemistry Reviews
• 出版年：2012
• 期刊代码：27_00108545
• 类别：ch
• 出版时间：August, 2012
• 卷：256
• 期：15-16
• 页码：1742-1761
• 文件大小：3810 K

摘要

This review surveys the different binding motifs and properties of hemicaged and caged complexes bearing tripodal units with a benzene platform. Complexes of inorganic cations and anions are the objects of this review. The 1:1 stoichiometry frequently observed for hemicage host-guest complexes constitutes a general paradigm for binding, one to which is not always adhered. Insight into the impact of preorganization, host selectivity and functionality will become apparent.