Bi-nuclear nitrosyl iron complex with 2-mercapto-imidazolyl: Synthesis, structure and magnetic properties

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• 作者：Natalia A. Sanina ; Sergey M. Aldoshin ; Tatiana N. Rudneva ; Nina I. Golovina ; Gennadyi V. Shilov ; Yurii M. Shulga ; Nicolai S. Ovanesyan ; Vladimir N. Ikorskiy and Viktor I. Ovcharenko
• 关键词：Iron– ; sulfur nitrosyl complexes ; 2-mercapto-imidazole ; X-ray analysis ; Mö ; ssbauer spectroscopy
• 刊名：Journal of Molecular Structure
• 出版年：2005
• 期刊代码：62_00222860
• 类别：ch
• 出版时间：2005
• 卷：752
• 期：1-3
• 页码：110-114
• 文件大小：189 K

摘要

Bi-nuclear neutral paramagnetic nitrosyl iron complex [Fe₂(C₃H₃N₂S)₂(NO)₄] (I) has been synthesized by the exchange reaction of Na₂Fe₂(S₂O₃)₂(NO)₄·4H₂O with imidazole-2-thiol. As it follows from X-ray analysis, complex I (space group P2(1)/n, Z