Recent advances in the chemistry of ruthenium carbido complexes

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• 作者：Shin Takemoto ; ^{takemoto@c.s.osakafu-u.ac.jp} ; Hiroyuki Matsuzaka ; ^{matuzaka@c.s.osakafu-u.ac.jp}
• 关键词：Ruthenium ; Carbido ; Carbene ; Carbyne ; Multiple bonds ; Clusters
• 刊名：Coordination Chemistry Reviews
• 出版年：2012
• 期刊代码：27_00108545
• 类别：ch
• 出版时间：March-April, 2012
• 卷：256
• 期：5-8
• 页码：574-588
• 文件大小：1591 K

摘要

Ruthenium has an extensive coordination chemistry with carbido ligands, forming diverse array of structures ranging from low-coordinate carbido complexes with Ru-C multiple bonds to high-nuclearity clusters with interstitial carbon atoms. These complexes have a close relationship to ruthenium carbene and carbyne complexes and have relevance to important catalytic processes such as the Fischer-Tropsch reaction and olefin metathesis. Ruthenium carbido clusters are versatile building blocks for high-nuclearity mixed-metal clusters of interesting structures and applications. This review aims to give an overview of recent progress in ruthenium carbido coordination chemistry with detailed coverage of the literature from 2000 to 2010.