Nucleophilic substitution reactions of adamantane derivatives with cyclophosphazenes

详细信息	查看全文 | 推荐本文 |

• 作者：陌lker Ü ; n ; Hanife 陌bi艧o臒lu ; ^{ibisoglu@gyte.edu.tr} ; Adem K谋l谋ç ; 艦ule 艦ahin Ü ; n ; Fatma Yuksel
• 关键词：Cyclophosphazene ; 1-Adamantylamine ; 1-Adamantanethiol ; Cyclotetraphosphazene ; 31P NMR
• 刊名：Inorganica Chimica Acta
• 出版年：2012
• 期刊代码：40_00201693
• 类别：ch
• 出版时间：30 May, 2012
• 卷：387
• 期：Complete
• 页码：226-233
• 文件大小：850 K

摘要

In the present work, the reactions of cyclophosphazenes with adamantane derivatives have been investigated. The geminal-bis- (3) and geminal-tetrakis- (4) compounds have been synthesized from the reaction of hexachloro-cyclotriphosphazatriene with 1-adamantanethiol. 2-(1鈥?Adamantylamino)-2,4,4,6,6-pentachlorocyclotriphosphazatriene (5) has been obtained from the reaction of hexachloro-cyclotriphosphazatriene with 1-adamantylamine. Furthermore, mono- (6) and non-geminal bis-substituted 1-adamantylamino cyclotetraphosphazene compounds 7 (2-trans-6) and 8 (2-cis-4) have been isolated from the reaction of octachlorocyclotetraphosphazatetraene with 1-adamantylamine. All compounds have been fully characterized by elemental analysis, mass, ¹H and ³¹P NMR spectroscopies. Molecular and crystal structures of 3 and 5-7 have been determined by X-ray crystallography. Compounds 3 and 4 are reported as the first examples for adamantylthio derivatives of cyclophosphazene in the literature. Compounds 5-8 have been also reported for the first time.