Synthesis and characterization of a new organic-inorganic hybrid zinc borate: [Zn(dab)_0.5(dab鈥?_0.5(B₄O₆(OH)₂)]路H₂O

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• 作者：Pei Zhao^a ; Lin Cheng^a ; Guo-Yu Yang^a ; ^b ; ^{ygy@fjirsm.ac.cn} ; ^{ygy@bit.edu.cn}
• 关键词：Zinc borate ; Hydrothermal synthesis ; Template ; Open-framework
• 刊名：Inorganic Chemistry Communications
• 出版年：2012
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：June, 2012
• 卷：20
• 期：Complete
• 页码：138-141
• 文件大小：676 K

摘要

A new organic-inorganic hybrid zinc borate [Zn(dab)_0.5(dab鈥?_0.5(B₄O₆(OH)₂)]路H₂O has been hydrothermally synthesized by using 1,4-diaminobutane (dab) as the linkers and characterized by means of elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction, respectively. This compound crystallizes in the monoclinic space group P2₁/c, a = 9.997(3) 脜, b = 8.371(3) 脜, c = 16.321(4) 脜, 尾 = 111.7(1)掳, V = 1268.8(7) 脜³, Z = 4. The structure contains ZnO₂N₂ tetrahedra, 1,4-dab and B₄O₇(OH)₂ clusters, which interconnect to form a new three-dimensional framework.