A N,N′-diacetate benzodioxotetraazamacrocycle and its transition metal complexes

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• 作者：Lacerda ; Sara ; Campello ; Maria Paula ; Santos ; Isabel C. ; Santos ; Isabel ; Delgado ; Rita
• 关键词：Macrocycles ; Monomeric Cu(II) benzodioxotetraazamacrocycle chloro complex ; Stability constants ; EPR of copper(II) complexes
• 刊名：Polyhedron
• 出版年：2005
• 期刊代码：87_02775387
• 类别：ch
• 出版时间：February 17, 2005
• 卷：24
• 期：3
• 页码：451-461
• 文件大小：308 K

摘要

Reaction of 2,9-dioxo-1,4,7,10-tetraazabicyclo[1.10.1]hexadeca-1(11),13,15-triene-4,7-diacetic acid (H₂L1) with CuCl₂脗脗2H₂O in ethanol at pH 6 led to the monomeric benzodioxochlorocomplex [Cu(L脗脗脗1)Cl] (1) (HL脗脗脗1