Epitaxial NaNbO3 thin films were deposited on single crystal Rh substrates by pulsed laser deposition. The epitaxial NaNbO3 thin film exhibited the tetragonally stained structure with a c/a ratio of about 1.04 and a good ferroelectric property with the high remanent polarization (Pr) of about 40 渭C/cm2. The piezoresponse force microscope study revealed that the epitaxial NaNbO3 thin film has a mosaic ferroelectric domain structure. A Pt/NaNbO3/Rh capacitor showed rapid ferroelectric switching behavior, which gives opportunity for a non-volatile memory application.