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- 作者：Yun Zhang
- 关键词：C-Glycoside ; d-Glucosamine ; Krapcho reaction ; cis-Dihydroxylation
- 刊名：The American Journal of Cardiology
- 出版年：2008
- 期刊代码：5_00029149
- 类别：med
- 出版时间：15 May 2008
- 卷：101
- 期：10
- 页码：1519
- 文件大小：40 K
摘要
The partial de novo synthesis of two new C-disaccharides containing d-glucosamine is described. The strategy is based on a hetero-Diels–Alder reaction leading to a 1:1 mixture of separable cycloadducts, which have been stereoselectively functionalized and converted into 
-d-Galp-(1→3)-C-d-GlcpNAc and -l-Galp-(1→3)-C-d-GlcpNAc.
-d-Galp-(1→3)-C-d-GlcpNAc and -l-Galp-(1→3)-C-d-GlcpNAc.