Convenient synthesis of copper (I) thiolates and related compounds

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• 作者：Nguyen ; Lynda M. ; Dellinger ; Megan E. ; Lee ; Jeffrey T. ; Quinlan ; Ronald A. ; Rheingold ; Arnold L. ; et. al.
• 关键词：Copper (I) ; Thiolates ; Phosphines ; Dithiocarbamates ; Dithiophosphates ; Tetrakis(1-imidazolyl)borate
• 刊名：Inorganica Chimica Acta
• 出版年：2005
• 期刊代码：40_00201693
• 类别：ch
• 出版时间：March 1, 2005
• 卷：358
• 期：4
• 页码：1331-1336
• 文件大小：169 K

摘要

Copper (I) salts of various anions including thiolates, diethyl dithiocarbamate, diethyl dithiophosphate, trithiocyanurate, 1-cyano-3-methylisothiourea, 2-aminothiazole, and tetrakis(1-imidazolyl)borate are conveniently synthesized by reducing copper (II) sulfate in aqueous ammonia. The addition of phosphine ligands to several of the products is demonstrated, and the crystal structure of [Cu₂(MBT)₂(DPPE)₃]脗脗Et₂O (MBT=2-mercaptobenzothiazolate, DPPE=1,2-bis(diphenylphosphino)ethane) is reported.