Crystal structure and self-assembly property of sandwich-type mixed (phthalocyaninato)(porphyrinato) rare earth double-decker complexes

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• 作者：Ranran Sun ; Xingcui Wu ; Zijuan Hao ; Xiaomei Zhang ; ^{zhangxiaomei@sdu.edu.cn}
• 关键词：Phthalocyanine ; Porphyrin ; Nanostructure ; Rare earth ; Self-assembly
• 刊名：Inorganica Chimica Acta
• 出版年：2012
• 期刊代码：40_00201693
• 类别：ch
• 出版时间：1 April, 2012
• 卷：384
• 期：Complete
• 页码：204-209
• 文件大小：1071 K

摘要

Two sandwich-type mixed (phthalocyaninato)(porphyrinato) rare earth double-decker complexes, M(Pc)(TPP) [H₂Pc = phthalocyanine; H₂TPP = meso-tetra(phenyl)porphyrin] (M = Eu, Lu) (1, 2) were synthesized and the structure of Lu(Pc)(TPP) was characterized by X-ray single-crystal diffraction method. Crystal data: triclinic, space group , Z = 2, C₇₇H₄₅Cl₃LuN₁₂, M_r = 1419.57, a = 12.573(5), b = 12.911(5), c = 22.935(5) 脜, 伪 = 103.793(5)掳, 尾 = 101.363(5)掳, 纬 = 93.682(5)掳, V = 3521(2) 脜³, 渭(Mo K伪) = 1.196 mm^鈭?, F(000) = 1426, R = 0.0590, and wR = 0.1639 for 9745 observed reflections with I > 2蟽(I). X-ray analysis reveals that the coordination polyhedron adopts a slightly distorted square-antiprismatic structure around the metal center. Both phthalocyanine and porphyrin ligands are saucer-shaped, with the skew angle of the two ligand planes approximately 45掳. The self-assembled nano-structures of both complexes 1 and 2 were systematically investigated by electronic absorption and Fourier transform infrared (FT-IR) spectroscopy, transmission electronic microscopy (TEM), scanning electronic microscopy (SEM), and X-ray diffraction (XRD) techniques, revealing the effect of molecular structure on the dimension of self-assembled nano-structures.