Electroviscoelasticity of liquid/liquid interfaces: fractional-order model
- 作者：Spasic ; Aleksandar M. ; Lazarevic ; Mihailo P.
- 关键词：Electroviscoelasticity ; Fractional-order model ; Deformable interfaces ; Finely dispersed systems ; Emulsions ; Double emulsions
- 刊名：Journal of Colloid and Interface Science
- 出版年：2005
- 期刊代码：125_00219797
- 类别：ch
- 出版时间：February 1, 2005
- 卷：282
- 期：1
- 页码：223-230
- 文件大小：240 K
摘要
A number of theories that describe the behavior of liquid–liquid interfaces have been developed and applied to various dispersed systems, e.g., Stokes, Reiner–Rivelin, Ericksen, Einstein, Smoluchowski, and Kinch. A new theory of electroviscoelasticity describes the behavior of electrified liquid–liquid interfaces in fine dispersed systems and is based on a new constitutive model of liquids. According to this model liquid–liquid droplet or droplet–film structure (collective of particles) is considered as a macroscopic system with internal structure determined by the way the molecules (ions) are tuned (structured) into the primary components of a cluster configuration. How the tuning/structuring occurs depends on the physical fields involved, both potential (elastic forces) and nonpotential (resistance forces). All these microelements of the primary structure can be considered as electromechanical oscillators assembled into groups, so that excitation by an external physical field may cause oscillations at the resonant/characteristic frequency of the system itself (coupling at the characteristic frequency). Up to now, three possible mathematical formalisms have been discussed related to the theory of electroviscoelasticity. The first is the tension tensor model, where the normal and tangential forces are considered, only in mathematical formalism, regardless of their origin (mechanical and/or electrical). The second is the Van der Pol derivative model, presented by linear and nonlinear differential equations. Finally, the third model presents an effort to generalize the previous Van der Pol equation: the ordinary time derivative and integral are now replaced with the corresponding fractional-order time derivative and integral of order Formula Not Shown .