Improvement and characterization of surfactant-modified Prussian blue screen-printed carbon electrodes for selective H₂O₂ detection at low applied potentials

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• 作者：P. Salazar^a ; ^{psalazar@ull.es} ; M. Martí ; n^a ; R.D. O&rsquo ; Neill^b ; R. Roche^a ; J.L. Gonzá ; lez-Mora^a
• 关键词：Prussian blue ; Screen-printed carbon electrodes (SPCEs) ; Surfactant ; Benzethonium chloride (BZTC) ; H2O2 sensor
• 刊名：Journal of Electroanalytical Chemistry
• 出版年：2012
• 期刊代码：pca22_15726657
• 类别：ce
• 出版时间：1 June, 2012
• 卷：674
• 期：Complete
• 页码：48-56
• 文件大小：1084 K

摘要

The development of a highly selective and sensitive H₂O₂ sensor, based on the electro-deposition of Prussian blue (PB) onto screen-printed carbon electrodes (SPCEs) modified by benzethonium chloride (BZTC), is described. This methodology provides a time-efficient method for producing stable films in the presence of a BZTC concentration which was optimized with respect to electrochemical and electroanalytical properties. Some parameters such as the amount of PB deposited, film thickness, reversibility, permeability, stability, electrocatalytic properties and sensitivity to H₂O₂ were considered in order to select the optimal sensor. Under optimal conditions (2 mM BZTC), the surface coverage and apparent diffusion coefficient for K⁺ displayed values of 6.4 卤 0.2 脳 10^鈭? mol cm^鈭? and 5.2 脳 10^鈭?1 cm² s^鈭?, respectively, one order of magnitude higher than without surfactant. The catalytic rate constant for the optimized film was 2.8 脳 10³ M^鈭? s^鈭? which was in good agreement with data found in the literature. BZTC(2 mM)/PB operating at 鈭? V vs. SCE displayed the highest H₂O₂ sensitivity (1.07 卤 0.03 A M^鈭? cm^鈭?, n = 5) reported in the literature to date for PB-modified SPCEs, and showed an excellent limit of detection (<10^鈭? M) and linearity range (up to 鈭?.5 mM). Sensors incorporating BZTC were significantly more stable in media containing Na⁺ ions, even at neutral pH, than unmodified devices, critical properties for sensor applications in biological environments. Finally, BZTC(2 mM)/PB-based sensors stored dry at room temperature over 4 months retained the 鈭?0%of their initial response to H₂O₂, a useful property for commercial applications.