Repetitive sideband-selective double frequency sweeps for sensitivity enhancement of MAS NMR of half-integer quadrupolar nuclei

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• 作者：M. Goswami ; P.J.M. van Bentum ; A.P.M. Kentgens ; ^{A.Kentgens@nmr.ru.nl}
• 关键词：Quadrupolar nuclei ; Albite ; Zoisite ; MAS ; Double frequency sweeps ; Adiabatic pulse ; CT ; ST ; Sensitivity enhancement
• 刊名：Journal of Magnetic Resonance
• 出版年：2012
• 期刊代码：126_10907807
• 类别：ch
• 出版时间：June, 2012
• 卷：219
• 期：Complete
• 页码：25-32
• 文件大小：944 K

摘要

A sensitivity enhancement scheme aiming at selective adiabatic inversion of a single set of satellite transition sidebands under magic angle spinning has been employed on samples of albite containing a single moderately distorted ²⁷Al site and zoisite containing two highly distorted octahedral ²⁷Al sites. Overall enhancements of 鈭?.5 for albite and 鈭? for the two AlO₆ sites of zoisite are reported by applying this scheme at different spinning speeds reflecting the versatility of this enhancement scheme which achieves significant signal-to-noise enhancements for the systems with moderately high quadrupolar coupling and high quadrupolar coupling. Repeating the sensitivity enhancement scheme and signal readout several times without allowing for spin-lattice relaxation leads to sensitivity enhancements of factors of 鈭? for albite and 鈭? for zoisite which substantially increases the detectability of the quadrupolar sites. The effectiveness of this scheme at high magnetic field under very fast magic angle spinning has been demonstrated. Finally, the possibility of performing spectral editing by selective enhancement of one of the quadrupolar sites in zoisite whilst keeping the other site unaffected has been explored.