摘要
We define an ensemble of projection operators, each of which has an exact associated Nakajima-Zwanzig master equation for quantum open system evolution. A mean field approximation for the memory kernels is introduced that yields a completely determined inhomogeneous master equation for every projection operator. A specific projection operator is then chosen so that the master equation optimally matches an abstract mathematical form which preserves positivity, complete positivity, and correctly equilibrates. We study a nitrogen vacancy center in diamond interacting with 13C impurities to illustrate the method.