A novel fluorous palladium catalyst for Suzuki reaction in fluorous media

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• 作者：Ming-Gui Shen ; Chun Cai ; Wen-Bin Yi
• 关键词：Suzuki reaction ; Palladium(II) perfluorooctanesulfonate ; Perfluorinated ligand ; Fluorous biphasic catalysis
• 刊名：Journal of Fluorine Chemistry
• 出版年：2007
• 期刊代码：52_00221139
• 类别：ch
• 出版时间：November 2007
• 卷：128
• 期：11
• 页码：1421-1424
• 文件大小：174 K

摘要

Palladium(II) perfluorooctanesulfonate [Pd(OSO₂R_f8)₂] catalyses the highly efficient Suzuki reaction in the presence of a catalytic amount of perfluoroalkylated-pyridine as a ligand in a fluorous biphase system (FBS). The fluorous phase containing the active palladium species is easily separated and can be reused several times without a significant loss of catalytic activity.