Supersaturated solid solution of niobium in copper by mechanical alloying
- 作者：Botcharova ; E. ; Heilmaier ; M. ; Freudenberger ; J. ; Drew ; G. ; Kudashow ; D. ; Martin ; U. ; Schultz ; L.
- 关键词：Transition metal alloys ; Mechanical alloying ; Mechanical properties ; Microstructure ; Transmission electron microscopy
- 刊名：Journal of Alloys and Compounds
- 出版年：2003
- 期刊代码：45_09258388
- 类别：ms
- 出版时间：March 10, 2003
- 卷：351
- 期：1-2
- 页码：119-125
- 文件大小：683 K
摘要
Alloys with both high strength and high conductivity have been produced by mechanical alloying. In the present study, copper was mechanically alloyed with 5, 10 and 20 at.%Nb using a planetary ball mill. The Cu–Nb phase diagram shows a negligibly low mutual solubility in the solid state, but high energy ball milling can largely extend the region of solid state solution. Previously, it was observed that niobium partly dissolves in the copper lattice during milling. The present investigation demonstrates that this limit can be extended to a strongly supersaturated Cu solid solution of up to 10 at.%Nb provided the appropriate mechanical alloying method is applied. The change in the powder microstructure was followed by scanning and transmission electron microscopy (TEM) as well as by X-ray diffraction (XRD) analysis. In the case of Cu–5%Nb and Cu–10%Nb a homogeneous single-phase microstructure was obtained after 30 h of milling. Elemental Nb could no more be detected, indicating the formation of a metastable supersaturated Cu–Nb solid solution.