Soot-free synthesis of C₆₀

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• 作者：Rodgers ; Ryan P. ; Reilly ; Peter T.A. ; Whitten ; William B. ; Ramsey ; J. Michael
• 关键词：A. Soot ; Fullerene ; B. Pyrolysis ; Carbonization ; C. Mass spectrometry
• 刊名：Carbon
• 出版年：2003
• 期刊代码：10_00086223
• 类别：ms
• 出版时间：2003
• 卷：41
• 期：8
• 页码：1469-1475
• 文件大小：240 K

摘要

A new synthetic medium for the production of C₆₀ has been found that does not produce soot. C₆₀ was produced in the liquid phase of an aerosol of precursor soot at 700°C. The precursor soot aerosol, a high temperature stable form of hydrocarbon, was produced by pyrolysis of acetylene at atmospheric pressure in a flow tube reactor. At 700°C, the effluent particles were found to contain PAHs, small hydrocarbons and fullerenes but no observable black material. However, when the reactor temperature was changed to 800°C, soot was also produced in the effluent particles along with PAHs and other small hydrocarbons, and the fullerene product disappeared. These results show a clear competition between the production of fullerenes and other forms of carbon. The filter-collected effluent was shown to be completely soluble in conventional solvents suggesting the possibility of an efficient cyclic synthetic process. Fullerenes were only found in the particle phase implying the first observed liquid phase synthesis of C₆₀.