The key role of support surface tuning during the preparation of catalysts from reverse micellar-synthesized metal nanoparticles

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• 作者：Agust&#xed ; n Mart&#xed ; nez ; Gonzalo Prieto
• 关键词：Cobalt catalyst ; Silica support ; Reverse microemulsion ; TEM
• 刊名：Catalysis Communications
• 出版年：2007
• 期刊代码：12_15667367
• 类别：ce
• 出版时间：October 2007
• 卷：8
• 期：10
• 页码：1479-1486
• 文件大小：800 K

摘要

Silica-supported cobalt catalysts have been prepared by depositing cobalt nanoparticles synthesized in reverse micellar systems. Two different reverse microemulsions comprising both a neutral (Triton X114) or an ionic (AOT) surfactant were used for the synthesis of nanoparticles. The materials have been characterized by ²⁹Si MAS NMR, XRD, FTIR, H₂-TPR, and TEM. Protection of the hydroxyl groups on the silica surface by silylation prior to loading of the cobalt nanoparticles has been found crucial for attaining the desired metal dispersions in the final catalyst owing to a higher chemical compatibility between the hydrophobic support surface and the microemulsion during the deposition step.