Transition Metal-Substituted Polyoxometalates Supported on MCM-41 as Catalysts in the Oxidation of Cyclohexane and Cyclooctane with H2O2

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• 作者：Jirarot Jatupisarnpong ; Wimonrat Trakarnpruk ; ^{Wimonrat.T@chula.ac.th}
• 刊名：Mendeleev Communications
• 出版年：2012
• 期刊代码：7_09599436
• 类别：ch
• 出版时间：May-June, 2012
• 卷：22
• 期：3
• 页码：152-153
• 文件大小：424 K

摘要

The Keggin type polyoxometalates (Bu4N)4HPW11CoO39, (Bu4N)4PW11FeO39, (Bu4N)4HPW11CuO39 and (Bu4N)4PW11VO40 have been synthesized and supported on MCM-41 to be used as catalysts for the solvent-free oxidation of cyclohexane and cyclooctane with H2O2.