Solvothermal synthesis and characterizations of three coordination polymers based on multicarboxylate ligand

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• 作者：Fei-Long Hu ; ^{hflphd@163.com} ; Zhen-ming Shen
• 关键词：C&ndash ; H&hellip ; 蟺 ; Hydrogen bonds ; Porous ; Polymer
• 刊名：Inorganic Chemistry Communications
• 出版年：2012
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：July, 2012
• 卷：21
• 期：Complete
• 页码：155-159
• 文件大小：1169 K

摘要

Three novel polymers, [Cd_1.5(oba)(pcla)(CH₃OH)](1), [Zn (oba)(4,4鈥?bpy)_1.5]₄(4,4鈥?bpy)₂(H₂O)₅ (2) and [Cu₂(oba)₂(DMF)](DMF)(H₂O)(3) (H₂oba = 4,4鈥?oxydibenzoic acid, Hpcla = picolinic acid) have been solvothermally synthesized and structurally characterized. 1 shows 2-D double layer structure with 1-D helix channels, while 2 and 3 display 3-D porous frameworks with different channels in their shapes and sizes. Moreover, complex 3 displays interesting hydrogen sorption behaviors and these materials are expected to afford potential applications.