Synthesis, structures and properties of the new lithium cobalt(II) phosphate Li₄Co(PO₄)₂

详细信息	查看全文 | 推荐本文 |

• 作者：R. Glaum^a ; ^{rglaum@uni-bonn.de} ; K. Gerber^a ; M. Schulz-Dobrick^b ; M. Herklotz^c ; F. Scheiba^c ; H. Ehrenberg^c
• 关键词：Cathode material ; Intercalation compound ; Solid-state reaction ; Thermal analysis ; UV/vis spectroscopy ; X-ray diffraction
• 刊名：Journal of Solid State Chemistry
• 出版年：2012
• 期刊代码：130_00224596
• 类别：ch
• 出版时间：April, 2012
• 卷：188
• 期：Complete
• 页码：26-31
• 文件大小：821 K

摘要

伪-Li₄Co(PO₄)₂ 尾-Li₃PO₄+LiCoPO₄ 尾-Li₄Co(PO₄)₂ 伪-Li₄Co(PO₄)₂According to HT-XRPD at 尾-Li₄Co(PO₄)₂ (Pnma, Z=2, 10.3341(8) 脜, b=6.5829(5) 脜, c=5.0428(3) 脜) is isostructural to 纬-Li₃PO₄. The powder reflectance spectrum of 伪-Li₄Co(PO₄)₂ shows the typical absorption bands for the tetrahedral chromophore [Co^IIO₄].