Anorthosites and Fe-Ti ore of the Kunene Intrusive Complex are characterised by low concentrations and strongly fractionated chondrite-normalised patterns of the highly siderophile elements. The abundance of highly siderophile elements is dominated by Fe-Ti oxides and traces of sulphides. The osmium isotopic composition and highly siderophile element distribution of the anorthosites are consistent with their derivation from a mantle-derived parental magma that was subject to fractionation of mafic minerals and variable extent of crustal contamination during its igneous evolution. Under conditions of the anorthosite formation Re behaves as a compatible element in fractionating titanomagnetite. The other highly siderophile elements are incorporated to a lesser extent into Fe-Ti oxides. During post-cumulus re-equilibration of Fe-Ti oxides Re is preferentially incorporated in magnetite whereas Pt displays preference for ilmenite.