A novel 1D T5(0)A(2) water tape incorporated in the channel of the first 3D silver-suberate framework

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• 作者：Geng-Geng Luo ; ^{ggluo@hqu.edu.cn} ; Dong-Liang Wu ; Li Liu ; Sheng-Hui Wu ; Dong-Xu Li ; Zi-Jing Xiao ; Jing-Cao Dai ; ^{djc@hqu.edu.cn}
• 关键词：1D water tape ; T5(0)A(2) motif ; irl Topology ; Suberate ; Pentameric water clusters ; Argentophilic interactions
• 刊名：Journal of Molecular Structure
• 出版年：2012
• 期刊代码：62_00222860
• 类别：ch
• 出版时间：25 April, 2012
• 卷：1014
• 期：Complete
• 页码：92-96
• 文件大小：759 K

摘要

A new three-dimensional (3D) silver(I) metal-organic framework (MOF) formulated as [Ag(sub)_0.5(bpp)]_n路5nH₂O (1) was prepared by the ultrasonic reaction of Ag₂O with H₂sub (H₂sub = suberic acid) in the presence of dipyridyl-containing ligand bpp (bpp = 1,3-bis(4-pyridyl)propane) and structurally characterized by single crystal X-ray diffraction. Topologically, when argentophilic interactions are taken into account, the resultant 3D Ag(I) MOF can alternatively be simplified to the irl (4² 路 6³ 路 8) topology. A self-assembled T5(0)A(2) water tape is confined in the channel of the framework and has been analyzed in comparison with known 1D water tapes constructed from pentameric water clusters. Moreover, photoluminescence property of 1 was investigated.