Experimental determination and modeling of densities and refractive indices of the binary mixtures of dimethylphthalate (or dimethyladipate) + 1-butanol, or +2-butanol, or +2-butanone at T = (288.15-323.15) K

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• 作者：Andjela B. Kne啪evi膰-Stevanovi膰^a ; Slobodan P. &Scaron ; erbanovi膰^b ; Bojan D. Djordjevi膰^b ; Du&scaron ; an K. Grozdani膰^b ; Jelena D. Smiljani膰^b ; Mirjana Lj. Kijev膷anin^b ; ^{mirjana@tmf.bg.ac.rs}
• 关键词：Excess molar volume ; Refractive index ; Mixtures ; Modeling
• 刊名：Thermochimica Acta
• 出版年：2012
• 期刊代码：110_00406031
• 类别：ch
• 出版时间：10 April, 2012
• 卷：533
• 期：Complete
• 页码：28-38
• 文件大小：403 K

摘要

The experimental density 蟻 and refractive index n_D of the six binary mixtures of dimethylphthalate and dimethyladipate with 1-butanol, 2-butanol and 2-butanone have been determined. All measurements of 蟻 and n_D have been performed simultaneously at eight temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15 and 323.15) K, and atmospheric pressure. Excess molar volumes and deviations of refractive indices 螖n_D were correlated by the Redlich-Kister equation.

In addition, correlation of have been performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) with two different types of mixing rules: the van der Waals (vdW1) and mixing rule introduced by Twu et al. (TCBT). For the refractive index calculations several mixing rules were employed: Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton and Oster.