Synthesis and photoluminescence properties of the high-brightness Eu³⁺-doped Sr₃Y(PO₄)₃ red phosphors

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• 作者：Baozhu Yang ; Zhiping Yang ; Yufeng Liu ; ^{liuyufeng4@126.com} ; Fachun Lu ; Panlai Li ; Yanmin Yang ; Xu Li
• 关键词：A. Powders ; solid state reaction ; C. Optical properties ; Luminescence ; Phosphors
• 刊名：Ceramics International
• 出版年：2012
• 期刊代码：13_02728842
• 类别：ms
• 出版时间：August, 2012
• 卷：38
• 期：6
• 页码：4895-4900
• 文件大小：637 K

摘要

A series of red-emitting phosphors Eu³⁺-doped Sr₃Y(PO₄)₃ have been successfully synthesized by conventional solid-state reaction, and its photoluminescence properties have been investigated. The excitation spectra reveal strong excitation bands at 392 nm, which match well with the popular emissions from near-UV light-emitting diode chips. The emission spectra of Sr₃Y(PO₄)₃:Eu³⁺ phosphors exhibit peaks associated with the ⁵D₀ 鈫?#xA0;⁷F_J (J = 0, 1, 2, 3, 4) transitions of Eu³⁺ and have dominating emission peak at 612 nm under 392 nm excitation. The integral intensity of the emission spectra of Sr₃Y_0.94(PO₄)₃:0.06Eu³⁺ phosphors excited at 392 nm is about 3.4 times higher than that of Y₂O₃:Eu³⁺ commercial red phosphor. The Commission Internationale de l鈥橢clairage chromaticity coordinates, the quantum efficiencies and decay times of the phosphors excited under 392 nm are also investigated. The experimental results indicate that the Eu³⁺-doped Sr₃Y(PO₄)₃ phosphors are promising red-emitting phosphors pumped by near-UV light.