A general dealloying strategy to nanoporous intermetallics, nanoporous metals with bimodal, and unimodal pore size distributions

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• 作者：W.B. Liu^a ; ^b ; ^{liuwenbo_8338@163.com} ; S.C. Zhang^a ; ^{csc@buaa.edu.cn} ; N. Li^b ; J.W. Zheng^a ; S.S. An^a ; Y.L. Xing^a
• 关键词：A. Intermetallics ; A. Copper ; B. Polarization ; B. SEM ; C. Dealloying ; C. Acid corrosion
• 刊名：Corrosion Science
• 出版年：2012
• 期刊代码：28_0010938x
• 类别：ch
• 出版时间：May, 2012
• 卷：58
• 期：Complete
• 页码：133-138
• 文件大小：965 K

摘要

We develop a general dealloying strategy to sequentially synthesize nanoporous intermetallics, nanoporous metals with bimodal, and unimodal pore size distributions. Typically, this strategy here was employed to fabricate nanoporous copper-based intermetallics (NPCBI), nanoporous copper (NPC) ribbons with bimodal, and unimodal pore size distributions by chemical dealloying of dual-phase Cu-M (M: Mg and Al) alloys with quasieutectic structures in an acidic solution. The results show that these porous products can be sequentially achieved by simply changing the dealloying times. Additionally, their morphological evolutions upon dealloying were investigated, and the formation mechanism is discussed.