Blue to orange emitters; palladium(0) monodentate phosphine complexes

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• 作者：Takuma Ohkubo ; Koichiro Takao ; Taro Tsubomura ; ^{tsubomura@st.seikei.ac.jp}
• 关键词：Luminescence ; Palladium(0) ; Phosphine complexes
• 刊名：Inorganic Chemistry Communications
• 出版年：2012
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：June, 2012
• 卷：20
• 期：Complete
• 页码：27-29
• 文件大小：316 K

摘要

Photoluminescence properties of palladium(0) complexes bearing monodentate phosphines are described. [Pd(P(o-tol)₃)₂] (o-tol = ortho-tolyl) emits relatively strong blue luminescence in the solid state. Whereas, [Pd(PCyPh₂)₃] (Cy = cyclohexyl) and [Pd(PCy₃)₂] show orange luminescence with a large Stokes-shift. The crystal structure analysis of [Pd(PCyPh₂)₃] reveals the trigonal planar geometry around the palladium atom.