The decrease in friction may result from weakening of the asperity contacts due to decarbonation of calcite induced by (1) flash heating or (2) mechanically-activated reactions. However, X-Ray powder diffraction and Raman Spectroscopy analyses do not reveal the presence of decarbonation products in the slipping zone. Instead, White Light Interferometry and Field Emission Scanning Electron Microscope observations reveal the presence of a smooth sliding surface made of nanometric-particles. The mechanical data can be fit by the rate- and state-dependent friction model or by a quadratic model (the latter proposed for powder lubrication). We conclude that flash heating and weakening and powder lubrication may operate together to decrease dynamic friction in limestone in experiments and, for the conditions investigated here, in nature.