Energy transfer process from polymer to rare earth complexes

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• 作者：Liang ; C. ; Li ; W. ; Hong ; Z. ; Liu ; X. ; Liu ; L. ; Zhao ; D. ; Liu ; Z. ; Peng ; J. ; Yu ; J. ; Xie ; M.
• 关键词：Energy transfer ; Electroluminescence ; Poly(N-vinylcarbazole) ; Rare earth complexes
• 刊名：Synthetic Metals
• 出版年：1997
• 期刊代码：77_03796779
• 类别：ph
• 出版时间：December, 1997
• 卷：91
• 期：1-3
• 页码：151-154
• 文件大小：277 K

摘要

The interaction between poly(N-vinylcarbazole) (PVK) and rare earth (RE) complexes, such as Eu(thenoytrifluoacetonato)₄₋(monopyridinium) (Eu(TTA)₄Py), Eu(nitrate)₃(monophenanthroline) (Eu(NO₃)₃phen) and Tb( acetylacetonato)₃(monophenanthroline) (Tb(AcA)₃phen), was investigated in solution as well as in films using the photoluminescence (PL) spectrum. In chloroform solution, the fluorescent intensity of the Eu(NO₃)₃phen was enhanced by PVK; however, the fluorescent intensity of the Tb complex was greatly quenched by PVK. Strongly characteristic emissions of Eu³⁺ and Tb³⁺ were observed in Eu and Tb complex-dispersed PVK films, respectively. The excitation spectra of Eu complex-dispersed PVK films and Tb complex-dispersed PVK film are very similar to that of the pure PVK film, indicating that effective energy transfer occurs from PVK to the RE complexes. Based on the above experimental results, three types of organic electroluminescence (EL) devices with structure of ITO/Eu(NO₃)₃phen : PVK/OXD-7/Al, ITO/Eu(TTA)₄Py : PVK/OXD-7/Al and ITO/Tb(AcA)₃phen : PVK/OXD-7/Al (ITO = indium-tin oxide) were fabricated. Bright red emission can be observed in the first and second devices while blight green light was emitted from the latter device.