Two different synthetic routes involving the reaction of dodecylamine or nicotinamide with crystalline lamellar vanadylphosphate

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• 作者：Machado ; Margarete O. ; de Farias ; Robson F. ; Airoldi ; Claudio
• 刊名：Journal of Physics and Chemistry of Solids
• 出版年：2004
• 期刊代码：69_00223697
• 类别：ch
• 出版时间：October, 2004
• 卷：65
• 期：10
• 页码：1697-1703
• 文件大小：215 K

摘要

The crystalline lamellar compound, VOPO₄·2H₂O, was employed as host to react with a long monoamine aliphatic chain, dodecylamine, and with an aromatic derivative, nicotinamide, using two distinct synthetic approaches: in the solid state and from aqueous solution. The resulting compounds were characterized by elemental analysis, infrared spectroscopy, X-ray diffractometry, thermogravimetry and SEM microscopy. From X-ray diffraction patterns, the calculated increase of the interlayer distance was 2.05 nm for the dodecylamine, containing product, which is in agreement with the intercalation process, and was observed with both reactions routes. On the contrary, the guest nicotinamide molecule was not inserted into the lamellar cavity. The reaction in the solid state caused a small modification of the phosphate microstructure, in comparison with the solution procedure. The aliphatic amine molecules are oriented in a bilayer inside the host cavity by forming an angle of 67° with the inorganic lamella. The thermal decomposition for both series of synthesized compounds did not demonstrate any difference in behavior.