Complex-shaped three-dimensional microstructures and photonic crystals generated in a polysiloxane polymer by two-photon microstereolithography
- 作者：Straub ; M. ; Nguyen ; L.H. ; Fazlic ; A. ; Gu ; M.
- 关键词：42.70.Qs ; 42.70.J ; 42.25.Bs ; 83.80.Cq ; Inorganic脙脙脙脙脙脙organic hybrid materials ; Polysiloxane polymers ; Two-photon photopolymerization ; Three-dimensional microstructures ; Photonic bandgap materials ; Stop gaps
- 刊名：Optical Materials
- 出版年：2004
- 期刊代码：81_09253467
- 类别：ch
- 出版时间：December, 2004
- 卷：27
- 期：3
- 页码：359-364
- 文件大小：443 K
摘要
Two-photon photopolymerization of inorganic芒芒芒organic hybrid materials permits the generation of complex-shaped three-dimensional microstructures at submicrometer resolution of structural elements. Due to their favorable optical, chemical and thermal properties these materials are particularly useful for photonic microdevice fabrication. Focussing ultrashort pulsed visible light into a modified commercially available polysiloxane polymer a Sydney Opera House design and a series of woodpile-type photonic crystals were fabricated. Fourier transform infrared spectroscopy revealed photonic stop gaps in the stacking direction at wavelengths varying from 6 to 4芒芒m upon reduction of the woodpile rod size. The structures allowed for the observation of higher-order stop gaps.