Oligomerization of phenylferrocenylacetylene under the action of WCl<sub>6sub>
- 作者：Inna V. Tatarinova ; Ol&rsquo ; ga A. Tarasova ; Marina V. Markova ; Lyudmila V. Morozova ; Al&rsquo ; bina I. Mikhaleva ; Boris A. Trofimov<sup> ; sup><sup>boris_trofimov@irioch.irk.rusup>
- 关键词：Phenylferrocenylacetylene ; Oligomerization ; Wolfram hexachloride ; Electroconductivity ; Paramagnetism
- 刊名：Journal of Organometallic Chemistry
- 出版年：2012
- 期刊代码：64_0022328x
- 类别：ch
- 出版时间：1 June, 2012
- 卷：706-707
- 期：Complete
- 页码：124-127
- 文件大小：197 K
摘要
Phenylferrocenylacetylene was found to be capable of oligomerizing in the presence of WCl<sub>6sub> (130聽掳C, 24聽h) to afford short polyenes (with about 5 monomer units in the macromolecule) in up to 鈭?0%yield. The polyenes synthesized are promising reactive macromonomers and building blocks for high-tech materials.