Hydrogen peroxide oxidation of aromatic hydrocarbons by immobilized iron(III)

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• 作者：Monfared ; Hassan Hosseini ; Amouei ; Zahra
• 关键词：Aromatic hydrocarbons ; Hydrogen peroxide ; Heterogeneous catalyst ; Oxidation
• 刊名：Journal of Molecular Catalysis A ; Chemical
• 出版年：2004
• 期刊代码：57_13811169
• 类别：ch
• 出版时间：August 3, 2004
• 卷：217
• 期：1-2
• 页码：161-164
• 文件大小：69.9 K

摘要

Supported iron(III) ions on neutral γ-alumina are an efficient catalyst for the oxidation of aromatic hydrocarbons with hydrogen peroxide in acetonitrile at 60°C. The catalyst is active in the low temperatue liquid phase oxidation of benzene, toluene, chlorobenzene, p-xylene, mesitylene, benzaldehyde with hydrogen peroxide. Conversions of 31–88%with respect to starting substrate were obtained within 6h. Oxidation on both the side chain and the aromatic ring of hydrocarbons occurred.