Formal synthesis of (鈭?-oleocanthal by means of a SmI₂-promoted intramolecular coupling of bromoalkyne with 伪,尾-unsaturated ester

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• 作者：Kazunori Takahashi ; Hiroshi Morita ; Toshio Honda ; ^{honda@hoshi.ac.jp}
• 关键词：Oleocanthal ; Samarium diiodide ; Bromoalkyne&ndash ; alkene coupling ; Formal synthesis ; Extra virgin olive oil
• 刊名：Tetrahedron Letters
• 出版年：2012
• 期刊代码：109_00404039
• 类别：ch
• 出版时间：27 June, 2012
• 卷：53
• 期：26
• 页码：3342-3345
• 文件大小：694 K

摘要

A novel approach to the synthesis of (鈭?-oleocanthal starting from d-ribose, in which a SmI₂-promoted intramolecular coupling of bromoalkyne with 伪,尾-unsaturated ester is a key step, has been developed.